Envoy Extraordinary and Minister Plenipotentiary to the Emperor of Brazil

Envoy Extraordinary and Minister Plenipotentiary to the United States of Brazil

• 1891–1894: Hugh Wyndham (later Sir Hugh Wyndham)
• 1894–1900: Constantine Phipps (later Sir Constantine Phipps)
• 1900–1906: Sir Henry Dering, 9th Bt.
• 1906–1915: Sir William Henry Doveton Haggard
• 1915–1919: Sir Arthur Peel

Ambassador

• 1919–1921: Sir Ralph Paget
• 1921–1925: Sir John Tilley
• 1925–1930: Sir Beilby Alston
• 1930–1935: Sir William Seeds
• 1935–1939: Sir Hugh Gurney
• 1939–1941: Sir Geoffrey Knox
• 1941–1944: Sir Noel Charles
• 1944–1947: Sir Donald Gainer
• 1947–1952: Sir Nevile Butler
• 1952–1956: Sir Geoffrey Thompson
• 1956–1958: Sir Geoffrey Harrison
• 1958–1963: Sir Geoffrey Wallinger
• 1963–1966: Sir Leslie Fry
• 1966–1969: Sir John Russell
• 1969–1973: Sir David Hunt
• 1973–1977: Sir Derek Dodson ^[6]
• 1977–1979: Sir Norman Statham
• 1979–1981: George Edmund Hall
• 1981–1984: William Harding (later Sir William Harding)
• 1984–1987: John Ure (later Sir John Ure)
• 1987–1992: Michael Newington
• 1992–1995: Peter Heap (later Sir Peter Heap)
• 1995–1999: Donald Haskell
• 1999–2004: Sir Roger Bone
• 2004–2008: Peter Collecott
• 2008–2013: Alan Charlton
• 2013–2017: Alex Ellis^[7]
• 2017–2020: Vijay Rangarajan^[8]
• 2021–2022: Peter Wilson^[9]
• 2022: Melanie Hopkins (acting)^[10]
• 2022–present: Stephanie Al-Qaq