The hexynes are a subgroup from the group of alkynes. It consists of several isomeric compounds having the formula C₆H₁₀.

The linear and branched members are:

• 1-Hexyne (n-butylacetylene)
• 2-Hexyne (methylpropylacetylene)
• 3-Hexyne (diethylacetylene)
• 3-methylpent-1-yne
• 4-methylpent-1-yne
• 4-methylpent-2-yne
• 3,3-dimethylbut-1-yne

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