Ionic bonding

Ionic bonding is a type of chemical bonding that involves the electrostatic attraction between oppositely charged ions, or between two atoms with sharply different electronegativities,[1] and is the primary interaction occurring in ionic compounds. It is one of the main types of bonding along with covalent bonding and metallic bonding. Ions are atoms (or groups of atoms) with an electrostatic charge. Atoms that gain electrons make negatively charged ions (called anions). Atoms that lose electrons make positively charged ions (called cations). This transfer of electrons is known as electrovalence in contrast to covalence. In the simplest case, the cation is a metal atom and the anion is a nonmetal atom, but these ions can be of a more complex nature, e.g. molecular ions like NH+
or SO2−
. In simpler words, an ionic bond results from the transfer of electrons from a metal to a non-metal in order to obtain a full valence shell for both atoms.

Sodium and fluorine atoms undergoing a redox reaction to form sodium ions and fluoride ions. Sodium loses its outer electron to give it a stable electron configuration, and this electron enters the fluorine atom exothermically. The oppositely charged ions typically a great many of them are then attracted to each other to form solid sodium fluoride.

It is important to recognize that clean ionic bonding — in which one atom or molecule completely transfers an electron to another — cannot exist: all ionic compounds have some degree of covalent bonding, or electron sharing. Thus, the term "ionic bonding" is given when the ionic character is greater than the covalent character – that is, a bond in which a large electronegativity difference exists between the two atoms, causing the bonding to be more polar (ionic) than in covalent bonding where electrons are shared more equally. Bonds with partially ionic and partially covalent character are called polar covalent bonds.

Ionic compounds conduct electricity when molten or in solution, typically not when solid. Ionic compounds generally have a high melting point, depending on the charge of the ions they consist of. The higher the charges the stronger the cohesive forces and the higher the melting point. They also tend to be soluble in water; the stronger the cohesive forces, the lower the solubility.[2]

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