Plutonium

Plutonium is a radioactive chemical element with the symbol Pu and atomic number 94. It is an actinide metal of silvery-gray appearance that tarnishes when exposed to air, and forms a dull coating when oxidized. The element normally exhibits six allotropes and four oxidation states. It reacts with carbon, halogens, nitrogen, silicon, and hydrogen. When exposed to moist air, it forms oxides and hydrides that can expand the sample up to 70% in volume, which in turn flake off as a powder that is pyrophoric. It is radioactive and can accumulate in bones, which makes the handling of plutonium dangerous.

Plutonium, 94Pu
Plutonium
Pronunciation/plˈtniəm/ (ploo-TOH-nee-əm)
Allotropessee Allotropes of plutonium
Appearancesilvery white, tarnishing to dark gray in air
Mass number[244]
Plutonium in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson
Sm

Pu

(Uqo)
neptuniumplutoniumamericium
Atomic number (Z)94
Groupgroup n/a
Periodperiod 7
Block  f-block
Electron configuration[Rn] 5f6 7s2
Electrons per shell2, 8, 18, 32, 24, 8, 2
Physical properties
Phase at STPsolid
Melting point912.5 K (639.4 °C, 1182.9 °F)
Boiling point3505 K (3228 °C, 5842 °F)
Density (near r.t.)19.85 g/cm3 (239Pu)[1]
when liquid (at m.p.)16.63 g/cm3
Heat of fusion2.82 kJ/mol
Heat of vaporization333.5 kJ/mol
Molar heat capacity35.5 J/(mol·K)
Vapor pressure
P (Pa) 1 10 100 1 k 10 k 100 k
at T (K) 1756 1953 2198 2511 2926 3499
Atomic properties
Oxidation states+2, +3, +4, +5, +6, +7, +8 (an amphoteric oxide)
ElectronegativityPauling scale: 1.28
Ionization energies
  • 1st: 584.7 kJ/mol
Atomic radiusempirical: 159 pm
Covalent radius187±1 pm
Spectral lines of plutonium
Other properties
Natural occurrencefrom decay
Crystal structure monoclinic
Speed of sound2260 m/s
Thermal expansion46.7 µm/(m⋅K) (at 25 °C)
Thermal conductivity6.74 W/(m⋅K)
Electrical resistivity1.460 µΩ⋅m (at 0 °C)
Magnetic orderingparamagnetic
Young's modulus96 GPa
Shear modulus43 GPa
Poisson ratio0.21
CAS Number7440-07-5
History
Namingafter dwarf planet Pluto, itself named after classical god of the underworld Pluto
DiscoveryGlenn T. Seaborg, Arthur Wahl, Joseph W. Kennedy, Edwin McMillan (1940–1941)
Main isotopes of plutonium
Iso­tope Abun­dance Half-life (t1/2) Decay mode Pro­duct
238Pu trace 87.74 y SF
α 234U
239Pu trace 2.41×104 y SF
α 235U
240Pu trace 6500 y SF
α 236U
241Pu syn 14 y β 241Am
SF
242Pu syn 3.73×105 y SF
α 238U
244Pu trace 8.08×107 y α 240U
SF
 Category: Plutonium
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Plutonium was first synthetically produced and isolated in late 1940 and early 1941, by a deuteron bombardment of uranium-238 in the 1.5-metre (60 in) cyclotron at the University of California, Berkeley. First, neptunium-238 (half-life 2.1 days) was synthesized, which subsequently beta-decayed to form the new element with atomic number 94 and atomic weight 238 (half-life 88 years). Since uranium had been named after the planet Uranus and neptunium after the planet Neptune, element 94 was named after Pluto, which at the time was considered to be a planet as well. Wartime secrecy prevented the University of California team from publishing its discovery until 1948.

Plutonium is the element with the highest atomic number to occur in nature. Trace quantities arise in natural uranium-238 deposits when uranium-238 captures neutrons emitted by decay of other uranium-238 atoms.

Both plutonium-239 and plutonium-241 are fissile, meaning that they can sustain a nuclear chain reaction, leading to applications in nuclear weapons and nuclear reactors. Plutonium-240 exhibits a high rate of spontaneous fission, raising the neutron flux of any sample containing it. The presence of plutonium-240 limits a plutonium sample's usability for weapons or its quality as reactor fuel, and the percentage of plutonium-240 determines its grade (weapons-grade, fuel-grade, or reactor-grade). Plutonium-238 has a half-life of 87.7 years and emits alpha particles. It is a heat source in radioisotope thermoelectric generators, which are used to power some spacecraft. Plutonium isotopes are expensive and inconvenient to separate, so particular isotopes are usually manufactured in specialized reactors.

Producing plutonium in useful quantities for the first time was a major part of the Manhattan Project during World War II that developed the first atomic bombs. The Fat Man bombs used in the Trinity nuclear test in July 1945, and in the bombing of Nagasaki in August 1945, had plutonium cores. Human radiation experiments studying plutonium were conducted without informed consent, and several criticality accidents, some lethal, occurred after the war. Disposal of plutonium waste from nuclear power plants and dismantled nuclear weapons built during the Cold War is a nuclear-proliferation and environmental concern. Other sources of plutonium in the environment are fallout from numerous above-ground nuclear tests, now banned.


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