The quantum pendulum is fundamental in understanding hindered internal rotations in chemistry, quantum features of scattering atoms, as well as numerous other quantum phenomena. Though a pendulum not subject to the small-angle approximation has an inherent nonlinearity, the Schrödinger equation for the quantized system can be solved relatively easily.
Using Lagrangian mechanics from classical mechanics, one can develop a Hamiltonian for the system. A simple pendulum has one generalized coordinate (the angular displacement ) and two constraints (the length of the string and the plane of motion). The kinetic and potential energies of the system can be found to be
This results in the Hamiltonian
The time-dependent Schrödinger equation for the system is
One must solve the time-independent Schrödinger equation to find the energy levels and corresponding eigenstates. This is best accomplished by changing the independent variable as follows:
This is simply Mathieu's differential equation
whose solutions are Mathieu functions.
Given , for countably many special values of , called characteristic values, the Mathieu equation admits solutions that are periodic with period . The characteristic values of the Mathieu cosine, sine functions respectively are written , where is a natural number. The periodic special cases of the Mathieu cosine and sine functions are often written respectively, although they are traditionally given a different normalization (namely, that their norm equals ).
The boundary conditions in the quantum pendulum imply that are as follows for a given :
The energies of the system, for even/odd solutions respectively, are quantized based on the characteristic values found by solving the Mathieu equation.
The effective potential depth can be defined as
The general solution of the above differential equation for a given value of a and q is a set of linearly independent Mathieu cosines and Mathieu sines, which are even and odd solutions respectively. In general, the Mathieu functions are aperiodic; however, for characteristic values of , the Mathieu cosine and sine become periodic with a period of .
For positive values of q, the following is true:
Here are the first few periodic Mathieu cosine functions for .
Note that, for example, (green) resembles a cosine function, but with flatter hills and shallower valleys.
- Bransden, B. H.; Joachain, C. J. (2000). Quantum mechanics (2nd ed.). Essex: Pearson Education. ISBN 0-582-35691-1.
- Davies, John H. (2006). The Physics of Low-Dimensional Semiconductors: An Introduction (6th reprint ed.). Cambridge University Press. ISBN 0-521-48491-X.
- Griffiths, David J. (2004). Introduction to Quantum Mechanics (2nd ed.). Prentice Hall. ISBN 0-13-111892-7.
- Muhammad Ayub, Atom Optics Quantum Pendulum, 2011, Islamabad, Pakistan., http://lanl.arxiv.org/PS_cache/arxiv/pdf/1012/1012.6011v1.pdf