2-(Diphenylphosphino)anisole

2-(Diphenylphosphino)anisole

2-(Diphenylphosphino)anisole

Chemical compound


2-(Diphenylphosphino)anisole is the organophosphorus compound with the formula (C6H5)2PC6H4-2-OCH3. It is a white solid that is soluble in organic solvents. The compound is used as a ligand in organometallic chemistry and homogeneous catalysis. It is the prototypical hemilabile ligand.[2] This compound is prepared from 2-bromoanisole.

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References

  1. Suomalainen, Pekka; Jääskeläinen, Sirpa; Haukka, Matti; Laitinen, Riitta H.; Pursiainen, Jouni; Pakkanen, Tapani A. (2000). "Structural and Theoretical Studies ofortho-Substituted Triphenylphosphane Ligands and Their Rhodium(I) Complexes". European Journal of Inorganic Chemistry. 2000 (12): 2607–2613. doi:10.1002/1099-0682(200012)2000:12<2607::AID-EJIC2607>3.0.CO;2-R.
  2. Jeffrey, J. C.; Rauchfuss, T. B. (1979). "Metal Complexes of Hemilabile Ligands. Reactivity and Structure of Dichlorobis(o-(diphenylphosphino)anisole)ruthenium(II)". Inorganic Chemistry. 18 (10): 2658–2666. doi:10.1021/ic50200a004.

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