Boratabenzene

Boratabenzene

Boratabenzene

Chemical compound

Boratabenzene is the heteroaromatic anion with the formula [C5H5BH]−. Derivatives of boratabenzene are ligands akin to cyclopentadienyl anion. sandwich or half-sandwich type complexes of many transition metals have been reported.[2][3] Electronically related heterocycles are adducts of borabenzene. The adduct C5H5B·pyridine exhibits properties of boratabenzene anion, i.e., it has the character C5H5B−-N+C5H5.

Quick Facts Names, Identifiers ...
Structure of Rh(C8H12)(η6-C5H5BH).[1]

See also

References

  1. [1]
    Yuan, Yuanyuan; Wang, Xiufang; Li, Yuxue; Fan, Liyan; Xu, Xin; Chen, Yaofeng; Li, Guangyu (2011). "Rapid Entry to Functionalized Boratabenzene Complexes through Metal-Induced Hydroboration at the Anionic 1-H-Boratabenzene Ligand". Organometallics. 30 (16): 4330–4341. doi:10.1021/om200396k.
  2. [2]
    Janiak, Christoph (2006). "Metallocene and Related Catalysts for Olefin, Alkyne and Silane Dimerization and Oligomerization". Coordination Chemistry Reviews. 250 (1–2): 66–94. doi:10.1016/j.ccr.2005.02.016.
  3. [3]
    Cui, Peng; Chen, Yaofeng (2016). "Boratabenzene Rare-earth Metal Complexes". Coordination Chemistry Reviews. 314: 2–13. doi:10.1016/j.ccr.2015.07.014.
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