Ferric_ammonium_oxalate

Ferric ammonium oxalate

Ferric ammonium oxalate

Chemical compound

Ferric ammonium oxalate (ammonium ferrioxalate, ammonium tris(oxalato)ferrate) is the ammonium salt of the anionic trisoxalato coordination complex of iron(III). It is a precursor to iron oxides, diverse coordination polymers, and Prussian Blue.[1][2] The latter behavior is relevant to the manufacture of blueprint paper. Ferric ammonium oxalate has also been used in the synthesis of superconducting salts with bis(ethylene)dithiotetrathiafulvalene (BEDT-TTF), see Organic superconductor.[3]

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See also

References

  1. [1]
    Vaucher, Sébastien; Li, Mei; Mann, Stephen (2000). "Synthesis of Prussian Blue Nanoparticles and Nanocrystal Superlattices in Reverse Microemulsions". Angewandte Chemie International Edition. 39 (10): 1793–1796. doi:10.1002/(SICI)1521-3773(20000515)39:10<1793::AID-ANIE1793>3.0.CO;2-Y. PMID 10934364.
  2. [2]
    Hussein, Gamal A.M.; Ismail, Hamdy M.; Attyia, Kairy M.E. (1995). "Physicochemical investigation of the decomposition products of ammonium metal carboxylates: Ammonium ferric oxalate hydrate". Journal of Analytical and Applied Pyrolysis. 31: 157–167. doi:10.1016/0165-2370(94)00825-L.
  3. [3]
    Martin, Lee (2018-12-01). "Molecular conductors of BEDT-TTF with tris(oxalato)metallate anions" (PDF). Coordination Chemistry Reviews. 376: 277–291. doi:10.1016/j.ccr.2018.08.013. ISSN 0010-8545.


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