Alloy_broadening
Alloy broadening is a spectral-line broadening mechanism caused by random distribution of the atoms in an alloy.[1]
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The alloy broadening is one of the line broadening mechanisms. The random distribution of atoms in an alloy causes a different material composition at different positions. In semiconductors and insulators the different material composition leads to different band gap energies. This gives different exciton recombination energies. Therefore, depending on the position where an exciton recombines the emitted light has a different energy. The alloy broadening is an inhomogeneous line broadening, meaning that its shape is Gaussian.