List_of_copper_alloys

List of copper alloys

List of copper alloys

Metal alloy with copper as its principal component


Copper alloys are metal alloys that have copper as their principal component. They have high resistance against corrosion. Of the large number of different types, the best known traditional types are bronze, where tin is a significant addition, and brass, using zinc instead. Both of these are imprecise terms. Latten is a further term, mostly used for coins with a very high copper content. Today the term copper alloy tends to be substituted for all of these, especially by museums.[1]

Example of a copper alloy object: a Neo-Sumerian "Foundation Nail" of Gudea, circa 2100 BC, made in the lost-wax cast method, overall: 17.5 x 4.5 x 7.3 cm, probably from modern-day Iraq, now in the Cleveland Museum of Art (Cleveland, Ohio, USA)

Copper deposits are abundant in most parts of the world (globally 70 parts per million), and it has therefore always been a relatively cheap metal. By contrast, tin is relatively rare (2 parts per million), and in Europe and the Mediterranean region, and even in prehistoric times had to be traded considerable distances, and was expensive, sometimes virtually unobtainable. Zinc was somewhere between these two in terms of rarity at 75 parts per million, but often harder to extract from its ores. Bronze with the ideal percentage of tin was therefore expensive and the proportion of tin often reduced to save cost. The discovery and exploitation of the Bolivian tin belt in the 19th century made tin far cheaper, although forecasts for future supplies are gloomy.

There are as many as 400 different copper and copper alloy compositions loosely grouped into the categories: copper, high copper alloy, brasses, bronzes, copper nickels, coppernickelzinc (nickel silver), leaded copper, and special alloys.

Composition

The similarity in external appearance of the various alloys, along with the different combinations of elements used when making each alloy, can lead to confusion when categorizing the different compositions. The following table lists the principal alloying element for four of the more common types used in modern industry, along with the name for each type. Historical types, such as those that characterize the Bronze Age, are vaguer as the mixtures were generally variable.

More information Family, Principal alloying element ...
More information Name, Nominal composition (percentages) ...
More information Family, CDA ...
More information Family, CDA ...

The following table outlines the chemical composition of various grades of copper alloys.

More information Family, CDA ...

Brasses

Binary Cu Si phase diagram, the base phase diagram for silicon bronzes
Binary Cu Al phase diagram, the base phase diagram for aluminium bronzes, generated using NIMS Open databases https://cpddb.nims.go.jp/cpddb/al-elem/alcu/alcu.htm - DOI https://doi.org/10.48505/nims.3060 and Computherm Pandat https://computherm.com/
Binary Cu Sn phase diagram, the base phase diagram for bronzes, generated using NIMS Open databases https://cpddb.nims.go.jp/cpddb/cu-elem/cusn/cusn.htm - DOI https://doi.org/10.48505/nims.3060 and Computherm Pandat https://computherm.com/
Binary Cu Zn phase diagram, the base phase diagram for brasses, generated using NIMS Open database https://cpddb.nims.go.jp/cpddb/cu-elem/cu_index.htm  Cu-Zn - DOI https://doi.org/10.48505/nims.3060 and Computherm Pandat https://computherm.com/

A brass is an alloy of copper with zinc. Brasses are usually yellow in colour. The zinc content can vary between few % to about 40%; as long as it is kept under 15%, it does not markedly decrease corrosion resistance of copper.

Brasses can be sensitive to selective leaching corrosion under certain conditions, when zinc is leached from the alloy (dezincification), leaving behind a spongy copper structure.

Bronzes

A bronze is an alloy of copper and other metals, most often tin, but also aluminium and silicon.

  • Aluminium bronzes are alloys of copper and aluminium. The content of aluminium ranges mostly between 5% and 11%. Iron, nickel, manganese and silicon are sometimes added. They have higher strength and corrosion resistance than other bronzes, especially in marine environment, and have low reactivity to sulphur compounds. Aluminium forms a thin passivation layer on the surface of the metal.
  • Bell metal
  • Phosphor bronze
  • Nickel bronzes, e.g. nickel silver and cupronickel
  • Speculum metal
  • UNS C69100

Precious metal alloys

Copper is often alloyed with precious metals like gold (Au) and silver (Ag).

More information Name, Cu [%] ...

† amount unspecified

See also


References

  1. Lyons, William C. and Plisga, Gary J. (eds.) Standard Handbook of Petroleum & Natural Gas Engineering, Elsevier, 2006
  2. National Bronze & Metals | Beryllium Copper
  3. Lewis Brass & Company | Copper Alloy Data
  4. Industrial Investment Castings - Franklin Bronze, retrieved 2009-09-07.
  5. Brass and Bronze Alloys, archived from the original on 2009-08-25, retrieved 2009-09-08.
  6. UNS C83400, retrieved 2009-09-08.
  7. UNS C86100, retrieved 2009-09-08.
  8. UNS C95410, retrieved 2009-09-08.
  9. UNS C95600, retrieved 2009-09-08.
  10. UNS C95700, retrieved 2009-09-08.
  11. UNS C87200, retrieved 2009-09-08.
  12. UNS C87400, retrieved 2009-09-08.
  13. UNS C87500, retrieved 2009-09-08.
  14. UNS C87600, retrieved 2009-09-08.
  15. UNS C87800, retrieved 2009-09-08.
  16. UNS C87900, retrieved 2009-09-08.

Bibliography

  • Oberg, Erik; Jones, Franklin D.; Horton, Holbrook L. (1992). Machinery's Handbook (24 ed.). New York: Industrial Press Inc. p. 501. ISBN 0-8311-2492-X.

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