List_of_esters

List of esters

List of esters

List of esters


In chemistry, an ester is a compound derived from an acid (organic or inorganic) in which the hydrogen atom (H) of at least one acidic hydroxyl group (−OH) of that acid is replaced by an organyl group (−R). Analogues derived from oxygen replaced by other chalcogens belong to the ester category as well (i.e. esters of acidic SH, SeH, TeH, PoH and LvH groups). According to some authors, organyl derivatives of acidic hydrogen of other acids are esters as well (e.g. amides), but not according to the IUPAC.[1]

An ester of carboxylic acid. R stands for any group (organic or inorganic) and R′ stands for organyl group.

An example of an ester formation is the substitution reaction between a carboxylic acid (R−C(=O)−OH) and an alcohol (R'OH), forming an ester (R−C(=O)−O−R'), where R and R′ are organyl groups, or H in the case of esters of formic acid. Glycerides, which are fatty acid esters of glycerol, are important esters in biology, being one of the main classes of lipids, and making up the bulk of animal fats and vegetable oils. Esters of carboxylic acids with low molecular weight are commonly used as fragrances and found in essential oils and pheromones. Phosphoesters form the backbone of DNA molecules. Nitrate esters, such as nitroglycerin, are known for their explosive properties, while polyesters are important plastics, with monomers linked by ester moieties. Esters of carboxylic acids usually have a sweet smell and are considered high-quality solvents for a broad array of plastics, plasticizers, resins, and lacquers.[2] They are also one of the largest classes of synthetic lubricants on the commercial market.[3]

By number of R' group carbons (R−C(=O)−O−R')

1 carbon

2 carbons

3 carbons

4 carbons

More information Name, Structure ...

5 carbons

More information Name, Structure ...

7 carbons

More information Name, Structure ...

8 carbons

More information Name, Structure ...

10 carbons

More information Name, Structure ...

By number of R group carbons (R−C(=O)−O−R')

0 carbons

More information Name, Structure ...

1 carbon

More information Name, Structure ...

2 carbons

3 carbons

More information Name, Structure ...

4 carbons

More information Name, Structure ...

5 carbons

More information Name, Structure ...

6 carbons

More information Name, Structure ...

7 carbons

8 carbons

More information Name, Structure ...

9 carbons

More information Name, Structure ...

10 carbons

More information Name, Structure ...

16 carbons

More information Name, Structure ...

List of ester odorants

Many esters of carboxylic acid have distinctive fruit-like odors, and many occur naturally in fruits and the essential oils of plants. This has also led to their common use in artificial flavorings and fragrances which aim to mimic those odors.

More information Ester name, Structure ...

Lactones

Lactones are a specific class cyclic carboxylic esters that are formed through intramolecular esterification.

More information Lactone name, Structure ...

References

  1. IUPAC, Compendium of Chemical Terminology, 2nd ed. (the "Gold Book") (1997). Online corrected version: (2006) "esters". doi:10.1351/goldbook.E02219
  2. Cameron Wright (1986). A worker's guide to solvent hazards. The Group. p. 48. ISBN 9780969054542.
  3. Reichel, Marco; Krumm, Burkhard; Vishnevskiy, Yury V.; Blomeyer, Sebastian; Schwabedissen, Jan; Stammler, Hans‐Georg; Karaghiosoff, Konstantin; Mitzel, Norbert W. (2019-12-16). "Solid‐State and Gas‐Phase Structures and Energetic Properties of the Dangerous Methyl and Fluoromethyl Nitrates". Angewandte Chemie International Edition. 58 (51): 18557–18561. doi:10.1002/anie.201911300. ISSN 1433-7851. PMC 6916544. PMID 31573130.
  4. Werner Reutemann and Heinz Kieczka "Formic Acid" in Ullmann's Encyclopedia of Industrial Chemistry 2002, Wiley-VCH, Weinheim. doi:10.1002/14356007.a12_013
  5. Merck Index, 12th Edition, 6089.
  6. "Methyl Propionate Hazardous Substance Fact Sheet" (PDF). New Jersey Department of Health and Senior Services.
  7. Methyl butyrate, thegoodscentscompany.com
  8. Methyl pentanoate, thegoodscentscompany.com
  9. Methyl benzoate, thegoodscentscompany.com
  10. Methyl anthranilate, thegoodscentscompany.com
  11. Methyl salicylate, thegoodscentscompany.com
  12. Methyl phenylacetate, thegoodscentscompany.com
  13. Methyl cinnamate, thegoodscentscompany.com
  14. Ethyl formate, thegoodscentscompany.com
  15. Ethyl acetate, thegoodscentscompany.com
  16. Ethyl propionate, thegoodscentscompany.com
  17. Ethyl lactate, thegoodscentscompany.com
  18. Ethyl butyrate, thegoodscentscompany.com
  19. Ethyl pentanoate, thegoodscentscompany.com
  20. Ethyl isovalerate, thegoodscentscompany.com
  21. Ethyl hexanoate, thegoodscentscompany.com
  22. Ethyl heptanoate, thegoodscentscompany.com
  23. Ethyl benzoate, thegoodscentscompany.com
  24. Ethyl salicylate, thegoodscentscompany.com
  25. Ethyl octanoate, thegoodscentscompany.com
  26. Ethyl cinnamate, thegoodscentscompany.com
  27. Ethyl decanoate, thegoodscentscompany.com

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