Quercitannic acid is one of the two forms of tannic acid^[1] found in oak bark and leaves.^[2] The other form is called gallotannic acid and is found in oak galls.

The quercitannic acid molecule is also present in quercitron, a yellow dye obtained from the bark of the Eastern black oak (Quercus velutina), a forest tree indigenous in North America. It is described as a yellowish brown amorphous substance.^[3]

In 1838, Jöns Jacob Berzelius wrote that quercitannate is used to dissolve morphine.^[4]

In 1865 in the fifth volume of "A dictionary of chemistry", Henry Watts wrote :

It exhibits with ferric salts the same reactions as gallotannic acid. It differs however from the latter in not being convertible into gallic acid, and not yielding pyrogallic acid by dry distillation. It is precipitated by sulfuric acid in red flocks. (Stenhouse, Ann. Ch. Pharm. xlv. 16.)
According to Rochleder (ibid lxiii. 202), the tannic acid of black tea is the same as that of oak-bark.^[5]

In 1880, Etti gave for it the molecular formula C₁₇H₁₆O₉. He described it as an unstable substance, having a tendency to give off water to form anhydrides (called phlobaphenes), one of which is called oak-red (C₃₄H₃₀O₁₇). For him, it was not a glycoside.^[6][7]

In Allen’s "Commercial Organic Analysis", published in 1912, the formula given was C₁₉H₁₆O₁₀.^[8]

Other authors gave other molecular formulas like C₂₈H₂₆O₁₅, while another formula found is C₂₈H₂₄O₁₁.^[9]

According to Lowe, two forms of the principle exist – one soluble in water, of the formula C₂₈H₂₈O₁₄, and the other scarcely soluble, C₂₈H₂₄O₁₂. Both are changed by the loss of water into oak red, C₂₈H₂₂O₁₁.^[10]

Quercitannic acid was for a time a standard used to assess the phenolic content in spices, given as quercitannic acid equivalent.^[11]