Thulium(II)_fluoride

Thulium(II) fluoride

Thulium(II) fluoride

Chemical compound


Thulium(II) fluoride is one of the fluoride salts of the lanthanide metal thulium, with the chemical compound of TmF2. It can react with zirconium tetrafluoride at 900 °C to form TmZrF6, which has a hexagonal structure.[1] In addition, low-temperature Mössbauer spectroscopy[2] and some theoretical studies[3] of thulium(II) fluoride have also been reported.

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References

  1. Ivanenko, O. P.; Kompanichenko, N. M.; Omel'chuk, A. O.; Rudkovs'ka, L. M.; Zinchenko, V. F. Reaction of zirconium tetrafluoride with nonstoichiometric lanthanide (samarium, europium, thulium, and ytterbium) fluorides. Ukrainskii Khimicheskii Zhurnal (Russian Edition), 2009. 75 (7-8): 83-88. ISSN: 0041-6045
  2. Triplett, B. B.; Dixon, N. S.; Boolchand, P.; Hanna, S. S.; Bucher, E. Low temperature Moessbauer studies of thulium compounds. Journal de Physique, Colloque, 1974. 6: 653-657. ISSN: 0449-1947 .DOI: 10.1051/jphyscol:19746144
  3. Michael Hülsen, Michael Dolg, Pascal Link, Uwe Ruschewitz (2011-06-25). "Improved valence basis sets for divalent lanthanide 4f-in-core pseudopotentials". Theoretical Chemistry Accounts. 129 (3–5): 367–379. doi:10.1007/s00214-010-0855-y. ISSN 1432-881X. S2CID 96979246. Retrieved 2019-03-26.{{cite journal}}: CS1 maint: multiple names: authors list (link)

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